NSF PAR Search | NSF Public Access Repository

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

Thermodynamic and Kinetic Modulation of Methylammonium Lead Bromide Crystallization Revealed by In Situ Monitoring

https://doi.org/10.1021/acs.cgd.4c00008

Ortoll-Bloch, Amnon G; Chen, Ying; Hiralal, Emily; Washton, Nancy M; Mueller, Karl T; De_Yoreo, James; Tao, Jinhui; Estroff, Lara A (June 2024, Crystal Growth & Design)

Full Text Available
Beyond π–π Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates

https://doi.org/10.1021/jacs.3c05380

Wang, Yiran; Nisbet, Matthew L.; Kamp, Kendall R.; Hiralal, Emily; Gautier, Romain; Halasyamani, P. Shiv; Poeppelmeier, Kenneth R. (August 2023, Journal of the American Chemical Society)

Full Text Available
Two Distinct Cu(II)–V(IV) Superexchange Interactions with Similar Bond Angles in a Triangular “CuV ₂ ” Fragment

https://doi.org/10.1021/acs.inorgchem.2c01691

Wang, Yiran; Fukuda, Masayuki; Nikolaev, Sergey; Miyake, Atsushi; Griffith, Kent J.; Nisbet, Matthew L.; Hiralal, Emily; Gautier, Romain; Fisher, Brandon L.; Tokunaga, Masashi; et al (July 2022, Inorganic Chemistry)

Full Text Available
Crystal structures of three copper(II)–2,2′-bipyridine (bpy) compounds, [Cu(bpy) ₂ (H ₂ O)][SiF ₆ ]·4H ₂ O, [Cu(bpy) ₂ (TaF ₆ ) ₂ ] and [Cu(bpy) ₃ ][TaF ₆ ] ₂ and a related coordination polymer, [Cu(bpy)(H ₂ O) ₂ SnF ₆ ] _n

https://doi.org/10.1107/S2056989021000633

Nisbet, Matthew L.; Hiralal, Emily; Poeppelmeier, Kenneth R. (February 2021, Acta Crystallographica Section E Crystallographic Communications)
null (Ed.)
We report the hydrothermal syntheses and crystal structures of aquabis(2,2′-bipyridine-κ 2 N , N ′)copper(II) hexafluoridosilicate tetrahydrate, [Cu(bpy) 2 (H 2 O)][SiF 6 ]·4H 2 O (bpy is 2,2′-bipyridine, C 10 H 8 N 2 ), (I), bis(2,2′-bipyridine-3κ 2 N , N ′)-di-μ-fluorido-1:3κ 2 F : F ;2:3κ 2 F : F -decafluorido-1κ 5 F ,2κ 5 F -ditantalum(V)copper(II), [Cu(bpy) 2 (TaF 6 ) 2 ], (II), tris(2,2′-bipyridine-κ 2 N , N ′)copper(II) bis[hexafluoridotantalate(V)], [Cu(bpy) 3 ][TaF 6 ] 2 , (III), and catena -poly[[diaqua(2,2′-bipyridine-κ 2 N , N ′)copper(II)]-μ-fluorido-tetrafluoridotin-μ-fluorido], [Cu(bpy)(H 2 O) 2 SnF 6 ] n , (IV). Compounds (I), (II) and (III) contain locally chiral copper coordination complexes with C 2 , D 2 , and D 3 symmetry, respectively. The extended structures of (I) and (IV) are consolidated by O—H...F and O—H...O hydrogen bonds. The structure of (III) was found to be a merohedral (racemic) twin.
more » « less
Full Text Available

Search for: All records